WANG Chao-hui, WANG Yu-cong, ZHANG Xin-yong, ZHANG Shao-bo, CHEN Qian, FU Hao
To comprehensively evaluate and accurately determine the performance of resin-based modified emulsified asphalt, and to further enhance the efficiency of demand-driven development and the service quality of high-grade resin materials, a full series of resin-based modified emulsified asphalts was systematically developed. These included formulations with single, binary, and ternary waterborne polymers. The mechanical, thermosensitive, waterproofing, rheological, and fatigue properties of the emulsified asphalts were examined. The effects of different waterborne resin polymer modifiers on cohesive strength, deformability, toughness, elasticity, low-temperature impact resistance, adhesion, and bonding were clarified. The temperature sensitivity, waterproofing ability, rheology, and fatigue life of resin-based modified emulsified asphalts were comprehensively evaluated. Based on the Pearson correlation coefficient method, the key indicators of mechanical and rheological properties were identified. A multidimensional performance correlation system was established, and functional relationships among critical performance indicators were revealed. The results show that different types of resin-based modified emulsified asphalts exhibit significant performance differences. Waterborne epoxy resin (WER) improves the mechanical, waterproofing, and high-temperature properties of emulsified asphalt. In particular, the binary WER/waterborne polyurethane (WPU) modified emulsified asphalt achieves a tensile strength of 5.98 MPa and a pull-off strength of 1.95 MPa at 25 ℃, with a creep recovery rate (R) of 97.36% at 76 ℃ and 3.2 kPa. The WPU-modified emulsified asphalt series exhibit superior cohesive strength, elasticity, toughness, low-temperature crack resistance, and fatigue performance, achieving an impact strength of 12.50 kJ·m-2 at -20 ℃. Upon incorporating waterborne acrylic (WA) or styrene-butadiene rubber (SBR), the WER/WPU/WA and WER/WPU/SBR ternary composite-modified emulsified asphalts demonstrate excellent flexibility, withstanding 180° bending without fracture at temperatures as low as -20 ℃. Additionally, their stiffness modulus (S) at -24 ℃ remained below 300 MPa, while the creep rate (m) exceeded 0.3. The WER/WPU/WA-modified emulsified asphalt exhibits outstanding toughness and fatigue life. Notably, quadratic functional relationships are observed between binder detachment rate and waterproofing performance, tensile strength and phase angle (δ) at 70 ℃, as well as impact strength at -20 ℃ and S at -18 ℃, with coefficients of determination (R2) of 0.97, 0.94, and 0.93, respectively. A power-law relationship is identified between fatigue life and complex shear modulus (G*) at 70 ℃, with R2 of 0.89.